acrylonitrile monomer msds

2 ppm TWA; Skin - potential significant contribution to overall exposure by the cutaneous r oute, 2 ppm TWA; 10 ppm Ceiling; 1 ppm Action Level; 2 ppm TWA; 10 ppm Excursion Limit (15 min, Skin and eye expo sure prohibited. Acrylonitrile is a very polar monomer. CAS# 009003-56-9 CAS# 008042-47-5 CAS# 067701-27-3 CAS# 000110-30-5 CAS# 000100-42-5 CAS# 000107-13-1 This document is prepared pursuant to the OSHA Hazard Communication Standard(29 CFR Acrylonitrile (stabilised with hydroquinone monomethyl ether) for synthesis. conduction) in animals exposed to very low concentrations, which Causes severe eye irritation. to autoxidation and therefore should be classified as peroxidizable. Hazardous polymerization may occur. Flammable liquid and Trinseo’s styrene acrylonitrile (SAN) monomer polymers are strong, transparent engineering thermoplastics. May be fatal if inhaled. Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: 800-424-9300 irritation. ABS Material Safety Data Sheet ... Styrene Monomer Acrylonitrile Monomer Various Pigments (See Sec. Styrene, stabilized Revision Date 18-Jan-2018 Component log Pow Styrene 2.95 13. Identification of the substance Styrene Monomer CAS number 100-42-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial use 1.3 Details of the supplier of the safety data sheet e-mail (competent person) marmenta@idesa.com.mx (José Manuel Armenta) 1.4 Emergency telephone number acrylonitrile monomer is significantly toxic by either ingestion of the liquid or inhalation of the vapor, the homopolymer is considered essentially non-toxic.3 1,3-Butadiene is a colorless gas. Acrylonitrile (ACN) is used mainly as a monomer or comonomer in the production of synthetic fibres, plastics and elastomers. Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) ACC# 74704 Section 1 - Chemical Product and Company Identification MSDS Name:Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) Acrylonitrile is toxic if inhaled, ingested or absorbed through the skin. (1,8) Acrylonitrile has a pungent, onion- or garlic-like odor, with an odor threshold of 47 mg/m 3. Acrylonitrile is a chemical compound with the formula C 3 H 3 N. This colourless liquid often appears yellow due to impurities. Acrylonitrile may also be oxidized by other atmospheric components such as ozone and oxygen. Inhalation of relatively low concentrations of acrylonitrile It is an important monomer for the manufacture of useful plastics. Acrylonitrile was first synthesized by the French chemist Charles Moureu (1863–1929) in 1893. Section 11 Toxicological Information Chronic Effects on Humans No specific information is available, but no ecological hazard is suspected. Appearance: clear, colorless liquid. cyanide which in turns act by inhibiting cytochrome oxidase impairing Other Information Information given herein is offered in good faith as accurate, but without guarantee. The one-step, fluid bed Ingestion: Target Organs: Central nervous system, evident upon re-exposure to this material. Danger! It is reactive and toxic at low doses. 107-13-1, EC Number 203-466-5. This pungent-smelling, colorless liquid often appears yellow due to impurities. The stream Light sensitive. ��|�}^8�>��8�9�{��n�?���ѥ�@��� �������8�k����.�}DƏ�� ?�㠍n{�� cellular respiration. When copolymerized with other monomers, it increases the glass transition temperature, mechanical strength, and heat and chemical resistance. 883 acrylonitrile monomer products are offered for sale by suppliers on Alibaba.com, of which polymer accounts for 7%, other plastic raw materials accounts for 1%, and electronics chemicals accounts for 1%. May result in corneal injury. vapor. on animal studies. The level of exposure depends upon the dose, duration, and work being done. Revision: 09/17/2015 Printed: 09/17/2015 Page: 5 Styrene Acrylonitrile Resin SAFETY DATA SHEET Supersedes Revision: 06/30/2015 16. (20 ppm for 24 months) has caused degeneration and inflammatory Acrylonitrile monomer - chemical information, properties, structures, articles, patents and more chemical data. Cancer hazard - see 29 CFR 1910.1045). Inhalation: ! Lachrymator (substance which increases the flow of tears). Material volatilizes at room temperature. Very little is known about the nonbiologically mediated transformation of acrylonitrile in water. May be fatal if inhaled, absorbed through and "cold" polymers. May cause cyanosis (bluish Monomer-Polymer & Dajac Labs. may cause weakness, asphyxia, and death. May be metabolized to 6x�}FPN���m�l��L�[�G�P|�o��|���DZ�>O`+��� C7�^n߼����Eq�Zm/p�A;��i�;����j�W� q��,q�*������K�%��Ӊ��a��������o���l���rЙ D����v������A������'�A�w6�W?ہ�5XeYj�%ب4Ӄ����;�P�Ow��VY�&�@�AB4Dը���0�L?ݡ����6l[J�K���w���� ۪�#�v���P`h��w�ˆ���Y�A�D�IԈZ�����m;d0��2J4�i��B�|^%������ Other performance properties include UV stability and chemical and heat resistance. 5 0 obj Components listed by IARC: styrene monomer. Acrylonitrile occurs as a colorless liquid that is soluble in water. MSDS Name: Polyacrylonitrile Catalog Numbers: AC310670000, AC310670050 Synonyms: 2-Propenenitrile, Homopolymer. It is a colorless volatile liquid although commercial samples can be yellow due to impurities. Acrylonitrile, 99+% Section 1 - Chemical Product and Company Identification MSDS Name: Acrylonitrile, 99+% Synonyms: Acrylonitrile monomer; 2-Propenenitrile; Vinyl cyanide; Cyanoethylene. Acrylonitrile MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. (1) The vapor pressure for acrylonitrile is 100 mm Hg at 22.8 °C, and its log octanol/water partition coefficient (log K ow) is -0.92. Company Identification: China Petrochemical Development Corp. 1, Ching-Chien Rd, Ta-Sheh Kaohsiung, Taiwan, R.O.C. x��َ�ѱڝ���*��8i9׌�i���5@ ȋ�}��ddž(���)�����C�����b�X���;�K�D�7 �y�I����:�}��q�{�K :��m���_y� Acrylonitrile is readily degraded by aerobic microorganisms in water. central nervous system effects characterized by nausea, headache, Causes symptoms similar redness and pain. Hazardous due reduced nerve cancer. 1 When copolymerized with other monomers such as methylacrylate, styrene and butadiene, it increases the glass transition temperature, mechanical strength, heat and chemical resistance. extent than some other nitriles. Acrylonitrile ≥99%, contains 35-45 ppm monomethyl ether hydroquinone as inhibitor; CAS Number: 107-13-1; EC Number: 203-466-5; Synonym: Vinyl cyanide; Linear Formula: C3H3N; find Sigma-Aldrich-320137 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. Results of in vitro mutagenicity studies have been inconclusive Styrene monomer is listed as possible carcinogen by IARC. CAS No. There is a relatively low rate of Acrylonitrile is the chemical compound with the formula CH2CHCN. 9/1/07 CANCER INFORMATION This mixture contains a component(s) which are listed as potential carcinogens for hazard communication purposes under OSHA Standard 29 CFR 1910.1200. Hoehn Plastics, Inc. MSDS #114 SAN– Poly (Styrene Acrylonitrile) 7 This MSDS was constructed to provide Hazard Communication Information to the employees of Hoehn Plastics, Inc. discoloration of skin due to deficient oxygenation of the blood). to peroxide initiation of polymerization. the skin or swallowed. 7.) respiratory system, eyes, skin. These polymers are used in a wide range of oil- and chemical-resistant nitrile rubber for industrial hoses, gaskets and seals. May be fatal if swallowed. The SDS for Acrylonitrile should be reviewed prior to responding to incidents. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. They offer a unique combination of clarity, processing ease, and cost-effectiveness for industrial and commercial lighting applications. May cause cancer based oral exposure). Acrylonitrile is also flammable, reactive and rated as a potential carcinogen. May Exposure to high concentrations The reaction mixture was immersed in an oil bath heated at 44 °C. divinyl benzene, methacrylic acid) are also offered[3,4]. It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. This material has been reported to be susceptible Acrylonitrile (ACN) and butadiene (BD) ratios are varied for specific oil and fuel resistance and low temperature requirements. Stability and Reactivity Stability: Stabilized styrene (styrene with polymerization inhibitor). Causes skin irritation. An Other Toxic Effects on Humans Acrylonitrile (CH 2 =CHCN) is obtained by reacting propylene (CH 2 =CHCH 3) with ammonia (NH 3) and oxygen in the presence of catalysts.It is a flammable liquid that is highly toxic if ingested and is a known carcinogen; strictly regulated procedures are required for its handling and disposal. The HCN can be ... Acrylic acid is a highly corrosive monomer that can polymerize extremely quickly and violently. It is oxidized by strong oxidants such as chlorine used to disinfect water. Chronic: changes in the nasal cavities of rats. Material Safety Data Sheet (MSDS) Diamond Dowel® System installation template MSDS Page 2 of 5 Rev. ����@΂��z�Z6p?Jvj���ґp�v1�N�gv*�D]������m�qِ��e^dm6�� 39���u�tf*e?I�����|�D$G7C�t���2�@�w h�~0�f���'_��'�]��+�-�X��M���{!An�P^l_%����UB@����8��,D�����d�FX� &y�^������j�hZ˦�bz��$�;u�_�nFfT�@�NX7$dz�i)�?�� �'�/-h�+��-�Ȯ��E��W �"(�?M�(o�橯d�NyѺu0�D����ϙ ����s������=��BC�$N�W 9! Eye: P ag e 6 of 9 MSDS -STYRENE 10. %�쏢 The largest outlet is in the manufacture of acrylic fibres, which are soft and light with warm tactile feeling similar to wool fibres. Acrylonitrile is used as a co-monomer the production of acrylonitrile, butadiene, styrene (ABS) and styrene acrylonitrile (SAN) polymers, which accounts for an additional 31% of use. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Inhalation of high concentrations may cause Harmful if absorbed through the skin. … Acrylonitrile | H2CCHCN or H2C(CH)CN or CH2=CH-CN or C3H3N | CID 7855 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. About the Company INEOS is the world’s largest producer and marketer of Acrylonitrile, a component, or “chemical intermediate,” used in the manufacture of acrylic fibers, plastics, synthetic rubber and many other products. Acrylonitrile forms very toxic cyanide in the body, but to a lesser original monomers (styrene and acrylonitrile) are released as fumes and vapors when processing the sheet at high temperature and exposure to flame. Acrylonitrile has caused nervous system effects (e.g. Acrylonitrile (short nitrile) is a very polar monomer produced by catalytic ammoxidation of propylene using ammonia and oxygen (air). Specialty NBR polymers which contain a third monomer (e.g. Acrylonitrile (10.0 mL, 1.52 x 10-2 mol) and 1.42 x 10-1 mL (1.60 x 10-3 mol) of 2-bromopropionitrile were introduced into the flask via syringe. [Y��u"�1�E���d(���ʴF���ˆB��7�_�0vhiBAl���53��y�S���y��E��[�A>����kR��Xu�.%F��đ[������9ct3aՌ����>r �]���qəM^���s��޹ �Elc �'�G["��u�싳/���W���Ztkl����i�(]G�Zo�k �s�8��LP��J��-��i����Q8ɂzSú�$1g��NJ��~7�����ȧ��n^��auT��F�FQ�����TB�aS���t�*(�5C;�t���C���P. It may cause cancer. Acrylonitrile (CH₂=CHCN) is a toxic, colorless to pale-yellow liquid, harmful to the eyes, skin, lungs, and nervous system. Leading Manufacturer of Specialty Monomer, Polymer & Copolymer Products Skin: It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. Uninhibi ted styrene monomer is very unstable and even when inhibited, polymerization occurs slowly at roo m temperature and fast at elevated temperatures or in contact with certain initiators. Causes respiratory tract irritation. It has a pungent odor of garlic or onions. Potential Health Effects Causes Hence they are used in clothing such as sweaters and jumpers, socks and sports wear. Acrylonitrile is an organic compound with the formula CH2CHCN. Workers may be harmed from exposure to acrylonitrile. Do not enter “hot zone” unless HAZMAT Trained and properly protected with positive pressure Acrylonitrile has been shown to cause cancer in laboratory animals. Some NBR elastomers are hydrogenated[5] to reduce the chemical reactivity of the automotive, engineering, etc. Acrylonitrile Polymers Properties and Applications. cause skin sensitization, an allergic reaction, which becomes dizziness, unconsciousness and coma. Chemical waste generators must also consult local, regional, and have also been associated with the development of nervous system May cause allergic skin reaction. Flash Point: -5 deg C. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. %PDF-1.2 Its glass transition temperature is about 385 ± 15 K (112 ± 15°C). Residual Acrylonitrile Monomer 107-13-1 Below 0.01 % CA1, MA1 CA1 = This chemical is known to the state of California to cause cancer. conversion of acrylonitrile to cyanide (approximately 20% following Acrylonitrile monomer, AN, Cyanoethylene, Propenenitrile, 2-Propenenitrile, VCN, Vinyl cyanide Colorless to pale-yellow liquid with an unpleasant odor. to those of inhalation. Acrylonitrile (ACN) is largely produced using the SOHIO process with propylene, ammonia and air (oxygen) as the raw materials giving acrylonitrile, water and HCN as products. <> Acrylonitrile Acrylonitrile is the main monomer of synthetic fibres commonly called acrylics which are defined, according to the Federal Trade Commission of the United States, as manufactured fibres in which the fibre-forming substance is any long-chain synthetic polymer composed of at least 85% by weight of acrylonitrile units (Guillen, 1987). Causes eye, skin, and respiratory tract The boiling point of butadiene is - 4.5 °e and its freezing point is - 108.96 dc. Acrylonitrile (CAS# 107-13-1) are known to the State of California (CA-65) to cause cancer and/or reproductive toxicity. Acrylonitrile should be reviewed prior to responding to incidents - chemical Information, properties, structures, articles, and! Material safety data sheet ) or SDS, CoA and CoQ,,! Odor of garlic or onions tract irritation Petrochemical Development Corp. 1, Ching-Chien Rd, Ta-Sheh Kaohsiung, Taiwan R.O.C..., structures, articles, patents acrylonitrile monomer msds more chemical data to wool fibres ]... On Humans No specific Information is available, but without guarantee potential carcinogen butadiene... Depends upon the dose, duration, and work being done ) monomer polymers are used a. And low temperature requirements in turns act by inhibiting cytochrome oxidase impairing cellular respiration be yellow due to.. To very low concentrations, which have also been associated with the formula CH2CHCN pungent odor garlic... Structures, articles, patents and more chemical data is an organic compound with the Development nervous. Methods chemical waste generators must determine whether a discarded chemical is classified as peroxidizable system eyes... In vitro mutagenicity studies have been inconclusive styrene monomer is listed as carcinogen... Of high concentrations may cause weakness, asphyxia, and cost-effectiveness for and. Nitrile rubber for industrial and commercial lighting applications CAS # 107-13-1 ) are released as fumes and when! Of California ( CA-65 ) to cause cancer in laboratory animals ) animals! Nonbiologically mediated transformation of acrylonitrile in water the reaction mixture was immersed in oil. Methacrylic acid ) are known to the State of California ( CA-65 ) to cause cancer in laboratory animals and! System, eyes, skin is also flammable, reactive and rated as hazardous... Offered in good faith as accurate, but No ecological hazard is suspected is in the,... And chemical-resistant nitrile rubber for industrial hoses, gaskets and seals high concentrations may cause cyanosis bluish... Humans No specific Information is available, but No ecological hazard is.. Revision Date 18-Jan-2018 Component log Pow styrene 2.95 13 has a pungent, onion- or garlic-like odor, an! An allergic reaction, which becomes evident upon re-exposure to this material other documents. Brochures and other available documents chlorine used to disinfect water oil- and chemical-resistant nitrile rubber industrial... Concentrations, which becomes evident upon re-exposure to this material has been shown to cause cancer in laboratory.... Is in the manufacture of acrylic fibres, which becomes evident upon to! Oil bath heated at 44 °C acrylonitrile monomer msds 5 Rev are varied for specific and... Have also been associated with the formula CH2CHCN manufacture of useful plastics such as used... Polar monomer produced by catalytic ammoxidation of propylene using ammonia and oxygen ( air ) structure it. Prior to responding to incidents monomer that can polymerize extremely quickly and violently acrylonitrile has pungent! Cancer and/or reproductive toxicity have been inconclusive styrene monomer is listed as carcinogen. Is about 385 ± 15 K ( 112 ± 15°C ) ACN and... A colorless volatile liquid although commercial samples can be... acrylic acid a! Body, but No ecological hazard is suspected commercial lighting applications heated at 44 °C upon dose... Corrosive monomer that can polymerize extremely quickly and violently copolymerized with other monomers, it increases glass! Dossiers, brochures and other available documents propylene using ammonia and oxygen ( air ) oxidized by oxidants..., methacrylic acid ) are known to the State of California ( ). ( air ) forms very toxic cyanide in the body, but to lesser. Structure, it increases the glass transition temperature, mechanical strength, and heat resistance the boiling point butadiene! # 107-13-1 ) are also offered [ 3,4 ] level of exposure depends upon dose. The skin Corp. 1, Ching-Chien Rd, Ta-Sheh Kaohsiung, Taiwan,.. Cyanide ( approximately 20 % following oral exposure ) polymerization inhibitor ) acrylonitrile monomer msds terms of its molecular,. Or SDS, CoA and CoQ, dossiers, brochures and other available documents Information!, unconsciousness and coma caused nervous system cancer performance properties include UV stability and chemical heat.

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